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IRON (II) OXIDE

IRON (II) OXIDE

CAS: 1345-25-1

Molecular Formula: FeO

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IRON (II) OXIDE - Names and Identifiers

Name IRON (II) OXIDE
Synonyms CI 77489
ironoxide(feo)
IRON (II) OXIDE
ironmonoxide[qr]
ironmonooxide[qr]
ironoxide[feo][qr]
naturalwuestite[qr]
CAS 1345-25-1
EINECS 215-721-8

IRON (II) OXIDE - Physico-chemical Properties

Molecular FormulaFeO
Molar Mass71.85
Density5.7 g/mL at 25 °C(lit.)
Melting Point1369°C
Water SolubilityInsoluble in water and alkalies. Soluble in HCl, H{2}SO{4}. Slightly soluble in HNO{3}Insoluble in water, alcohol and alkali. Soluble in hydrochloric acid and sulfuric acid. Slightly soluble in nitric
Appearance5 Mesh
Merck14,4052
Storage ConditionRoom Temprature
StabilityStable. Incompatible with strong oxidizing agents. Highly flammable.
SensitiveAir Sensitive
MDLMFCD00016095
UseUses Use of ferrous oxide: It is used as a pigment and has applications in cosmetics and tattoo inks. Ferrous oxide is also used in porcelain making to make the glaze green.

IRON (II) OXIDE - Risk and Safety

Hazard SymbolsF - Flammable
Flammable
Risk Codes11 - Highly Flammable
Safety DescriptionS16 - Keep away from sources of ignition.
S33 - Take precautionary measures against static discharges.
S7/9 -
UN IDsUN 3178 4.1/PG 2
WGK Germany-
TSCAYes

IRON (II) OXIDE - Upstream Downstream Industry

Downstream ProductsSodium thiocyanate
Iron oxide black

IRON (II) OXIDE - Security information

toxic substance data 1345-25-1(Hazardous Substances Data)
Last Update:2024-04-10 22:29:15

IRON (II) OXIDE - Nature

EPA chemical information Ferrous oxide (1345-25-1)
Last Update:2024-04-10 22:29:15

IRON (II) OXIDE - Uses and synthesis methods

Introduction

Ferrous oxide is one of the oxides of iron. Its appearance is blue-gray powder, the chemical formula is FeO, and it is covalently combined with oxygen in the oxidation state of iron and oxygen. Its mineral form is kyrite (kyrite). Ferrous oxide is often easily confused with rust, but the main component of rust is hydrated iron oxide. Ferrous oxide is an anintegral compound, in which the ratio of iron and oxygen will change, ranging from Fe0.84O to Fe0.95O.

structure

Ferrous oxide belongs to the cubic crystal system (similar to the crystal structure of sodium chloride). Six oxygen atoms are connected around each iron atom to form an octahedral coordination, and six iron atoms are connected around each oxygen atom in the same situation. The reason for the occurrence of non-integral compounds is that because divalent iron is easily oxidized to ferric iron, a small amount of divalent iron in FeO is replaced with ferric iron, occupying tetrahedral voids in the lattice.

At less than 200K, the crystal structure of ferrous oxide will change slightly, becoming rhombus and antiferromagnetic.

Preparation

FeO can be made by heating ferrous oxalate under isolated air conditions.

Formation of ferrous oxide

FeO can also be obtained by reacting iron oxide with carbon monoxide (heating iron oxide in a reducing flame) at 900°C.

Last Update:2024-04-10 22:39:43
IRON (II) OXIDE
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View History
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Downstream Products for IRON (II) OXIDE
Sodium thiocyanate
Iron oxide black
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